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K-LTSCR: An Industry-Specific Low-Temperature Denitrification Catalyst

Korea Institute of Energy Research

Korea Institute of Energy Research (KIER)

Air Quality

K-LTSCR: An Industry-Specific Low-Temperature Denitrification Catalyst

Low-temperature denitrification catalyst technology that removes nitrogen oxides (NOx) with high efficiency (over 90%) even at low temperatures (180°C)

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CATEGORYAir Quality

Technology Overview

  • A flue gas denitrification catalyst technology that removes more than 90% of nitrogen oxides even in low-temperature flue gas at 180 °C, where commercial SCR (Selective Catalytic Reduction) systems fail to perform optimally

  • We are currently conducting 100 Nm³/h-scale pilot demonstrations targeting flue gases from industrial sites such as cement kilns and steelmaking sintering furnaces to establish a database of operating conditions and design parameters for each industry; this technology enables compliance with stricter emission standards without the need to reheat the flue gas

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Key Technology Features

  • Low-temperature denitrification catalyst materials and manufacturing technology that achieve a denitrification efficiency of over 90% in the 180 °C low-temperature range

  • Operational technology that eliminates the temperature-rising load on existing SCR systems by accommodating a wide operating temperature range of 170–400 °C

  • Demonstration technology that utilizes a 100 Nm³/h-class pilot plant to verify performance and durability using actual flue gas from industrial sites and to derive problem-solving strategies

  • Catalyst module design and operational know-how tailored to the flue gas characteristics (sulfur, chlorine, and alkali components; temperature; flow rate) of each facility can be provided as a comprehensive package

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Competitive Advantages of the Technology

Existing Technology

This Technology

Commercial SCR systems operate normally only at temperatures above 250 °C, requiring the reheating of low-temperature exhaust gas; in the steel industry, 38% of the operating costs for exhaust gas purification equipment are consumed by the cost of heating the gas to the required temperature

By operating at 180°C, the reheating process is eliminated, enabling annual savings of approximately 22.5 billion won in reheating costs and energy savings of about 63% based on the steelmaking sintering process

Catalysts currently supplied in Korea are V, W, and Ti-based low-to-medium-temperature types, whose denitrification efficiency drops sharply below 240°C; there are no documented cases of achieving an efficiency of 90% or higher at 180°C.

By achieving a denitrification efficiency approximately 30% higher than that of existing operating facilities in the low-temperature range (180–220°C), it is possible to meet emission standards even under stricter regulatory conditions

Catalyst replacement cycles are short (2–3 months for incinerators) due to poisoning caused by sulfur, chlorine, and alkali components in the flue gas, resulting in significant replacement costs

With poisoning resistance five times that of commercial catalysts from overseas manufacturers (Companies C and S), the replacement cycle can be extended

Experimental and Demonstration Data

  • During the initial startup phase of an LNG combined-cycle power plant, at temperatures below 200 °C or lower, where high concentrations of NOx are emitted, and efficiency in the low-temperature range (180–220 °C) improved by approximately 30% compared to SCR systems in existing facilities. It is estimated that this enables an additional annual reduction of approximately 7 metric tons of NOx at this power plant.

  • Compared to overseas catalysts (Companies C and S) supplied to commercial SCR facilities, this catalyst was confirmed to offer up to 2.3 times higher low-temperature denitrification efficiency and 5 times greater resistance to poisoning

Expected Benefits by Industry

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Applications

Application FieldsApplicable Products
  • Denitrification of Flue Gas from Cement Calcination Kilns
  • DeNOx of Flue Gas from Steel Sintering Furnaces
  • Flue Gas Denitrification for Incinerators
  • NOx Reduction During the Start-up Phase of LNG Combined Cycle Power Plants
  • Low-Temperature SCR Honeycomb Catalyst Module
  • Low-Temperature SCR Reactors and Systems
  • Replacement Catalysts for Existing SCR Systems

TRL Stage

  1. 1
  2. 2
  3. 3
  4. 4
  5. 5
  6. 6
  7. 7
  8. 8
  9. 9
Basic research (1–3)Prototype (4–6)Commercialization (7–9)

TRL 6–7

TRL 6–7: A demonstration is currently underway (2024–2025) using a 100 Nm³/h-class pilot plant to evaluate performance and durability during 500 hours of continuous operation using actual flue gas.

# Low-Temperature Denitrification# SCR# Nitrogen oxides# Air Quality# Cement# In Season
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